Synthetic non-heme iron catalyst for C-H bond halogenation

Wenduo WANG

Synthetic non-heme iron catalyst for C-H bond halogenation

Wenduo WANG

Department of Science and Environmental Studies (SES)

Research output: Thesis › Honours Projects (HP)

Abstract

In the natural condition, hydroxylation is preferred over halogenation due to the involvement of molecular oxygen. Halogenation in the inner bio-environment requires a complex co-effect of enzyme chains or groups, which is hard to simulate in artificial reactions. Thus, developing an effective and selective model for halogenation is important for synthetic chemistry study. This project proposed synthetic iron(III) complexes for C-H halogenation. Ligands based on 6-(Aminomethyl)-2,2'-bipyridine were synthesized and identified, while corresponding iron(III) complexes were examined.

Original language	English
Qualification	Bachelor of Education (Honours)
Supervisors/Advisors	CHOW, Cheuk Fai Stephen 周卓輝, Supervisor
Publication status	Published - 2022

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 4 Quality Education

Keywords

Tetracoordinate
Iron(III) complex
Synthetic model
C-H halogenation
Honours Project (HP)
Bachelor of Education (Honours) (Science) (Five-year Full-time)
Programme code: A5B085
Course code: SCG4025

Other files and links

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title = "Synthetic non-heme iron catalyst for C-H bond halogenation",

abstract = "In the natural condition, hydroxylation is preferred over halogenation due to the involvement of molecular oxygen. Halogenation in the inner bio-environment requires a complex co-effect of enzyme chains or groups, which is hard to simulate in artificial reactions. Thus, developing an effective and selective model for halogenation is important for synthetic chemistry study. This project proposed synthetic iron(III) complexes for C-H halogenation. Ligands based on 6-(Aminomethyl)-2,2'-bipyridine were synthesized and identified, while corresponding iron(III) complexes were examined.",

author = "Wenduo WANG",

year = "2022",

language = "English",

type = "Honours Projects (HP)",

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TY - THES

T1 - Synthetic non-heme iron catalyst for C-H bond halogenation

AU - WANG, Wenduo

PY - 2022

Y1 - 2022

N2 - In the natural condition, hydroxylation is preferred over halogenation due to the involvement of molecular oxygen. Halogenation in the inner bio-environment requires a complex co-effect of enzyme chains or groups, which is hard to simulate in artificial reactions. Thus, developing an effective and selective model for halogenation is important for synthetic chemistry study. This project proposed synthetic iron(III) complexes for C-H halogenation. Ligands based on 6-(Aminomethyl)-2,2'-bipyridine were synthesized and identified, while corresponding iron(III) complexes were examined.

AB - In the natural condition, hydroxylation is preferred over halogenation due to the involvement of molecular oxygen. Halogenation in the inner bio-environment requires a complex co-effect of enzyme chains or groups, which is hard to simulate in artificial reactions. Thus, developing an effective and selective model for halogenation is important for synthetic chemistry study. This project proposed synthetic iron(III) complexes for C-H halogenation. Ligands based on 6-(Aminomethyl)-2,2'-bipyridine were synthesized and identified, while corresponding iron(III) complexes were examined.

UR - https://www.lib.eduhk.hk/pure-data/pub/202202265/202202265_1.pdf

UR - https://www.lib.eduhk.hk/pure-data/pub/202202265/202202265_2.pdf

M3 - Honours Projects (HP)

ER -

Synthetic non-heme iron catalyst for C-H bond halogenation

Abstract

UN SDGs

Keywords

Other files and links

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