Abstract
A series of polynuclear copper(I) and gold(I) alkynyl complexes, [Cu₃(μ-dppm)₃(μ₃-η¹-CC-Np)₂]BF₄ (1), [Cu₃(μ-dppm)₃(μ₃-η¹-CCC₆H₄CN-4)₂]BF₄ (2) and [{AuP(Tol-p)₃(CC)}₂Np-1,5] (3), have been synthesized and shown to exhibit rich photoluminescence at ambient and low temperatures. The electrochemistry of the complexes has also been studied in detail by cyclic voltammetry. Copyright © 2014 Elsevier Ltd. All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 178-184 |
| Journal | Polyhedron |
| Volume | 83 |
| Early online date | 14 Jun 2014 |
| DOIs | |
| Publication status | Published - 24 Nov 2014 |
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phosphine
Electrochemistry
electrochemistry
phosphines
Gold
Cyclic voltammetry
ambient temperature
Copper
Photoluminescence
gold
photoluminescence
copper
synthesis
Temperature
Citation
Lo, H.-S., Zhu, N., Au, V. K.-M., & Yam, V. W.-W. (2014). Synthesis, characterization, photophysics and electrochemistry of polynuclear copper(I) and gold(I) alkynyl phosphine complexes. Polyhedron, 83, 178-184. doi: 10.1016/j.poly.2014.06.006Keywords
- Copper(I)
- Gold(I)
- Alkynyl
- Luminescence
- Polynuclear