Synthesis, characterization, electrochemistry and photophysical studies of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands

Siu-Tung LAM; Nianyong ZHU; Ka Man Vonika AU; Vivian Wing-Wah YAM

doi:10.1016/j.poly.2014.03.051

Synthesis, characterization, electrochemistry and photophysical studies of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands

Siu-Tung LAM, Nianyong ZHU, Ka Man Vonika AU, Vivian Wing-Wah YAM

Department of Science and Environmental Studies (SES)

Research output: Contribution to journal › Article

12 Citations (Scopus)

Abstract

A class of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands, [Re(CO)₃(N^N)(CC-C₆H₄-CHO)] (N^N = α,α′-diimine ligand), has been successfully synthesized and characterized, and the X-ray crystal structure of one of the complexes has been determined. Electrochemical and photophysical studies have been performed to study the effect of the variation of the diimine ligand on the redox and optical properties of the rhenium(I) complexes. Copyright © 2014 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	10-16
Journal	Polyhedron
Volume	86
Early online date	08 Apr 2014
DOIs	https://doi.org/10.1016/j.poly.2014.03.051
Publication status	Published - 28 Jan 2015

Citation

Lam, S.-T., Zhu, N., Au, V. K.-M., & Yam, V. W.-W. (2015). Synthesis, characterization, electrochemistry and photophysical studies of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands. Polyhedron, 86, 10-16. doi: 10.1016/j.poly.2014.03.051

Keywords

Rhenium(I)
Diimine
Alkynyl
Electrochemistry
Photoluminescence

Access to Document

10.1016/j.poly.2014.03.051

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