Preparation and photocatalytic behavior of MoS2 and WS2 nanocluster sensitized TiO2

Wing Kei HO, Jimmy C. YU, Jun LIN, Jiaguo YU, Puishan LI

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458 Citations (Scopus)

Abstract

A new approach has been developed for the fabrication of visible light photocatalysts. Nanoclusters of MoS2 and WS2 are coupled to TiO2 by an in situ photoreduction deposition method taking advantage of the reducing power of the photogenerated electrons from TiO2 particles. The photocatalytic degradation of methylene blue and 4-chlorophenol in aqueous suspension has been employed to evaluate the visible light photocatalytic activity of the powders. The blue shift in the absorption onset confirms the size quantization of MS2 nanoclusters, which act as effective and stable sensitizers, making it possible to utilize visible light in photocatalysis. Quantum size effects alter the energy levels of the conduction and valence band edges in the coupled semiconductor systems, which favors the interparticle electron transfer. In addition, the coupled systems are believed to act in a cooperative manner by increasing the degree of charge carrier separation, which effectively reduces recombination. Copyright © 2004 American Chemical Society.
Original languageEnglish
Pages (from-to)5865-5869
JournalLangmuir
Volume20
Issue number14
DOIs
Publication statusPublished - 2004

Citation

Ho, W. K.; Yu, J. C.; Lin, J.; Yu, J. G.; Li, P. S. (2004). Preparation and Photocatalytic Behavior of MoS2 and WS2 Nanocluster Sensitized TiO2. Langmuir, 20(14), 5865-5869. doi: 10.1021/la049838g

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