Abstract
Rare-earth thulium (Tm³⁺) doped yttrium oxide (Y₂O₃) host single crystals are promising “eye-safe” laser materials. However, the mechanisms of photoluminescence and energy transfer in Tm³⁺ doped Y₂O₃ crystals are not yet understood at the fundamental level. Here, we synthetize a series of Y₂O₃:Tm³⁺ samples by the sol-gel method. Our experimental results show that the most intensive absorption line of the ³H₆ → ¹D₂ transition occurs at 358 nm, and the strongest emission line of the ¹D₂ → ³F₄ transition is located at 453 nm, which are in good agreement with the calculations of 363 nm and 458 nm, respectively. By using the CALYPSO structural search method, the ground state structure of Y₂O₃:Tm³⁺ withP2 space group symmetry is uncovered. The complete energy levels, including free-ion LS terms and crystal-field LSJ multiplet manifolds, of Y₂O₃:Tm³⁺ are obtained based on our developed WEPMD method. The present findings show that our WEPMD method can be used in experiments to elucidate the underlying mechanisms of photoluminescence and energy transfer in Tm³⁺ doped Y₂O₃ crystals, which offer insights for further understanding of other rare-earth doped laser materials. Copyright © 2023 Royal Society of Chemistry.
Original language | English |
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Pages (from-to) | 25273-25279 |
Journal | Physical Chemistry Chemical Physics |
Volume | 25 |
Issue number | 37 |
Early online date | Aug 2023 |
DOIs | |
Publication status | Published - Oct 2023 |