Photocatalytic conversion of CO₂ to CO by a copper(II) quaterpyridine complex

Zhenguo GUO, Fei YU, Ying YANG, Chi Fai LEUNG, Siu-Mui NG, Chi-Chiu KO, Claudio COMETTO, Tai-Chu LAU, Marc ROBERT

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24 Citations (Scopus)

Abstract

The invention of efficient systems for the photocatalytic reduction of CO2 comprising earth‐abundant metal catalysts is a promising approach for the production of solar fuels. One bottleneck is to design highly selective and robust molecular complexes that are able to transform the CO2 gas. The CuII quaterpyridine complex [Cu(qpy)]2+ (1) is found to be a highly efficient and selective catalyst for visible‐light driven CO2 reduction in CH3CN using [Ru(bpy)3]2+ (bpy: bipyridine) as photosensitizer and BIH/TEOA (1,3‐dimethyl‐2‐phenyl‐2,3‐dihydro‐1H‐benzo[d]imidazole/triethanolamine) as sacrificial reductant. The photocatalytic reaction is greatly enhanced by the presence of H2O (1–4 % v/v), and a turnover number of >12 400 for CO production can be achieved with 97 % selectivity, which is among the highest of molecular 3d CO2 reduction catalysts. Results from Hg poisoning and dynamic light scattering experiments suggest that this photocatalyst is homogenous. To the best of our knowledge, 1 is the first example of molecular Cu‐based catalyst for the photoreduction of CO2. © 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim.
Original languageEnglish
Pages (from-to)4009-4013
JournalChemSusChem
Volume10
Issue number20
DOIs
Publication statusPublished - 2017

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Carbon Monoxide
Copper
Catalysts
Catalyst poisoning
Photosensitizing Agents
Reducing Agents
Patents and inventions
Dynamic light scattering
Photocatalysts
Gases
Metals
Experiments

Citation

Guo, Z., Yu, F., Yang, Y., Leung, C. -F., Ng S. -M., Ko, C. -C., Cometto, C., Lau, T. -C., and Robert, M.(2017). Photocatalytic conversion of CO₂ to CO by a copper(II) quaterpyridine complex. ChemSusChem, 10(20), 1-6. doi: 10.1002/cssc.201701354

Keywords

  • Carbon dioxide reduction
  • Copper
  • Homogeneous catalysis
  • Photocatalysis
  • Transition metals