In situ immobilization of cadmium in soil by stabilized biochar-supported iron phosphate nanoparticles

Yanzhe XU, Zhanqiang FANG, Po Keung Eric TSANG

Research output: Contribution to journalArticles

26 Citations (Scopus)

Abstract

The potential for nanoscale phosphate amendments to remediate heavy metal contamination has been widely investigated, but the strong tendency of nanoparticles to form aggregates limits the application of this technique in soil. This study synthesized a composite of biochar-supported iron phosphate nanoparticle (BC@Fe₃(PO₄)₂) stabilized by a sodium carboxymethyl cellulose to improve the stability and mobility of the amendment in soil. The sedimentation test and column test demonstrated that BC@Fe₃(PO₄)₂ exhibited better stability and mobility than iron phosphate nanoparticles. After 28 days of simulated in situ remediation, the immobilization efficiency of Cd was 60.2 %, and the physiological-based extraction test bioaccessibility was reduced by 53.9 %. The results of sequential extraction procedures indicated that the transformation from exchangeable (EX) Cd to organic matter (OM) and residue (RS) was responsible for the decrease in Cd leachability in soil. Accordingly, the pot test indicated that Cd uptake by cabbage mustard was suppressed by 86.8 %. Compared to tests using iron phosphate nanoparticles, the addition of BC@Fe₃(PO₄)₂ to soil could reduce the Fe uptake of cabbage mustard. Overall, this study revealed that BC@Fe₃(PO₄)₂ could provide effective in situ remediation of Cd in soil. Copyright © 2016 Springer-Verlag Berlin Heidelberg.
Original languageEnglish
Pages (from-to)19164-19172
JournalEnvironmental Science and Pollution Research
Volume23
Issue number19
Early online dateJun 2016
DOIs
Publication statusPublished - Oct 2016

Citation

Xu, Y., Fang, Z., Tsang, E. P. (2016). In situ immobilization of cadmium in soil by stabilized biochar-supported iron phosphate nanoparticles. Environmental Science and Pollution Research, 23(19), 19164-19172.

Keywords

  • Iron phosphate
  • Biochar
  • Cd-polluted soil
  • In situ remediation
  • Mobility

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