Cleaner conversion of bamboo into carbon fibre with favourable physicochemical and capacitive properties via microwave pyrolysis combining with solvent extraction and chemical impregnation

Su Shiung LAM, Elfina AZWAR, Wanxi PENG, Yiu Fai TSANG, Nyuk Ling MA, Zhenling LIU, Young-Kwon PARK, Eilhann E. KWON

Research output: Contribution to journalArticle

Abstract

Bamboo was converted into carbon fibre using a novel approach combining microwave pyrolysis, solvent extraction, and chemical impregnation. The employment of solvent extraction and chemical impregnation transformed natural bamboo into bamboo fibre with yield of 64 wt% that comprised of 87 wt% cellulose, 4 wt% lignin and 9 wt% hemicellulose deemed desirable for conversion into carbon fibre. The subsequent use of microwave pyrolysis transformed the bamboo fibre to form carbon fibre; the effects of microwave irradiation time and microwave power (two key process parameters) on properties of carbon fibre were investigated. Microwave pyrolysis provides a rapid heating rate (30 °C/min) with relatively shorter process time (20 min) compared to that performed by conventional pyrolysis method, thus leading to a relatively lower electric consumption and providing a potentially cost-saving and energy-efficient approach to produce carbon fibre. The production and properties of carbon fibre produced were affected by irradiation time and microwave power. The carbon fibre obtained was detected to have high fixed carbon (80 wt%), carbon element (87%), high BET surface area (475 m²/g) and fibres in small diameter (≤1 μm). It also shows desirable features comprising low content of moisture (<6 wt%), inorganic elements of Na, K, S, Mg (≤5%) and ash (1 wt%), allowing the carbon fibre to have more active sites and making it a cleaner product rather than polluting the environment whereas a high ash content could lead to undesired catalytic reactions and emission of potentially hazardous metallic components present in the ash. Combined with the detection of positive capacitive behaviour, the carbon fibre shows great potential to be used as an electrode for energy storage application. The results disclose that microwave pyrolysis combining with solvent extraction and chemical impregnation can be a cleaner approach to transform bamboo into carbon fibre with favourable physicochemical and capacitive properties. Copyright © 2019 Elsevier Ltd. All rights reserved.
Original languageEnglish
Article number117692
JournalJournal of Cleaner Production
Volume236
Early online dateJul 2019
DOIs
Publication statusPublished - Nov 2019

Fingerprint

Bamboo
bamboo
Solvent extraction
Impregnation
pyrolysis
Carbon fibers
Pyrolysis
Microwaves
Ashes
ash
Fibers
irradiation
chemical
microwave
Carbon fiber
Microwave
Carbon
Microwave irradiation
carbon
Lignin

Citation

Lam, S. S., Azwar, E., Peng, W., Tsang, Y. F., Ma, N. L., Liu, Z., . . . Kwon, E. E. (2019). Cleaner conversion of bamboo into carbon fibre with favourable physicochemical and capacitive properties via microwave pyrolysis combining with solvent extraction and chemical impregnation. Journal of Cleaner Production, 236. Retrieved from https://doi.org/10.1016/j.jclepro.2019.117692

Keywords

  • Pyrolysis
  • Microwave
  • Bamboo
  • Carbon fibre
  • Energy