A highly active and robust solid-supported polypyridylruthenium(II) catalyst for the oxidation of alcohols and alkenes by cerium(IV) and periodate in water

Zongmin HU, Hongxia DU, Chi Fai LEUNG, Haojun LIANG, Tai-Chu LAU

Research output: Contribution to journalArticlespeer-review

10 Citations (Scopus)

Abstract

The species cis-[Ruᴵᴵ(2,9-Me₂phen) ₂(OH2)₂]²⁺, both in homogeneous solution and supported on Dowex cation-exchange resin, is a highly active and robust catalyst for the oxidation of alcohols and alkenes in water at room temperature, using Ce(IV) and IO₄⁻ as terminal oxidants, with a turnover number (TON) of >10⁴. Copyright © 2011 American Chemical Society.

Original languageEnglish
Pages (from-to)12288-12292
JournalIndustrial & Engineering Chemistry Process Design and Development
Volume50
Issue number21
DOIs
Publication statusPublished - 02 Nov 2011

Citation

Hu, Z., Du, H., Leung, C.-F., Liang, H., & Lau, T.-C. (2011). A highly active and robust solid-supported polypyridylruthenium(II) catalyst for the oxidation of alcohols and alkenes by cerium(IV) and periodate in water. Industrial and Engineering Chemistry Research, 50(21), 12288–12292. doi: 10.1021/ie201637r

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